← Kompas SemesterATOMIC STRUCTURE // 3D ORBITALS
three atoms · mouse: drag to rotate
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Atomic structure // sheet 1 of 1 // three specimens, in 3D
Three atoms. One set of rules.
Hydrogen, neon, sodium. Scroll to fly into each: first the orbital clouds, then the nucleus.
Specimen 01// hydrogen, orbital
One electron, one spherical cloud.
An electron does not circle the nucleus on a track. The cloud shows where you would probably find it:
each dot is one possible position, and denser means more likely. Hydrogen's electron sits in the 1s orbital, a sphere.
▸ electron configuration
fig. 1
1s1
1s cloud
fig. 1 — one electron, one orbital, half full. That empty half is why hydrogen bonds so readily.
Specimen 01// hydrogen, nucleus
A nucleus of one proton.
Fly in far enough and the cloud thins out around a single proton. The most common form of hydrogen has no neutrons at all.
▸ nucleus
fig. 2
1
proton
0
neutrons
+1
charge
fig. 2 — scale break: the nucleus is drawn thousands of times too large. At true scale it would be invisible.
Specimen 02// neon, orbitals
Every orbital full. Nothing left over.
Neon's ten electrons fill 1s (2), 2s (2) and all three 2p orbitals (6). The p orbitals are dumbbells
pointing along x, y and z. A full set of them adds up to a perfectly round cloud, and a full outer shell is why neon barely reacts.
▸ electron configuration
fig. 3
1s2 2s2 2p6
1s2s2p
fig. 3 — the sizes between shells are schematic; the shapes within each orbital are the real probability distributions.
Specimen 02// neon, nucleus
Ten protons, ten neutrons.
Neon-20, the common isotope, packs ten protons (orange) and ten neutrons (grey) together. The strong force holds them
at a range far shorter than the size of the electron clouds around them.
▸ nucleus
fig. 4
10
protons
10
neutrons
20
mass no.
fig. 4 — equal numbers of protons and neutrons is typical for light, stable nuclei.
Specimen 03// sodium, orbitals
One electron, out in a new orbital.
Sodium is neon plus one electron. The second shell is full, so the newcomer goes into 3s, a much bigger sphere.
The ten inner electrons shield it from most of the nucleus's pull, so it is easy to pull away. That is why sodium reacts so readily.
▸ electron configuration
fig. 5
1s2 2s2 2p6 3s1
1s2s2p3s (valence)
fig. 5 — same core as neon (fig. 3), plus one electron in the outermost orbital.
Specimen 03// sodium, nucleus
One more neutron than proton.
Sodium-23 has eleven protons and twelve neutrons. As nuclei get heavier they need proportionally more neutrons
to stay together against the protons' electrical repulsion.
▸ nucleus
fig. 6
11
protons
12
neutrons
23
mass no.
fig. 6 — the neutron-to-proton ratio climbs as atoms get heavier.
The rules// how orbitals fill
Three rules decide every atom here.
Behind them is one picture: neon's three 2p orbitals, equal in energy and at right angles to each other.
Electrons fill them one at a time before any pairing up.
▸ filling order
fig. 7
Aufbau
lowest energy first
Pauli
max 2 per orbital, opposite spin
Hund
spread out before pairing
fig. 7 — break Pauli and the state is impossible. Break Aufbau or Hund and you get an excited, higher-energy atom.
Now build one yourself.
pick any electron count from 1 to 11
Live// build your own atom
Watch the orbitals fill, in order.
Drag to any electron count. Orbitals fill by the three rules, and the cloud density follows the electron count.
Z = 1 · hydrogen1s¹
▸ the three 2p orbitals (they fill only after 2s is full)
·2pₓ
·2pᵧ
·2p_z
// drag the slider: every atom from Z=1 to Z=11 fills the same way.
The sheet, complete
Same rules. Different outcomes.
Neon has a full outer shell; sodium has one lone electron in the next one. The difference between a noble gas and a reactive metal is one electron's address.